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BUREAU OF MINES 
INFORMATION CIRCULAR/1989 



Analyses of Natural Gases, 1988 



By J. E. Hamak and Stella Sigler 



UNITED STATES DEPARTMENT OF THE INTERIOR 



Mission: As the Nation's principal conservation 
agency, the Department of the Interior has respon- 
sibility for most of our nationally-owned public 
lands and natural and cultural resources. This 
includes fostering wise use of our land and water 
resources, protecting our fish and wildlife, pre- 
serving the environmental and cultural values of 
our national parks and historical places, and pro- 
viding for the enjoyment of life through outdoor 
recreation. The Department assesses our energy 
and mineral resources and works to assure that 
their development is in the best interests of all 
our people. The Department also promotes the 
goals of the Take Pride in America campaign by 
encouraging stewardship and citizen responsibil- 
ity for the public lands and promoting citizen par- 
ticipation in their care. The Department also has 
a major responsibility for American Indian reser- 
vation communities and for people who live in 
Island Territories under U.S. Administration. 



Information Circular 9225 

w 



Analyses of Natural Gases, 1988 



By J. E. Hamak and Stella Sigler 



UNITED STATES DEPARTMENT OF THE INTERIOR 
Manuel Lujan, Jr., Secretary 

BUREAU OF MINES 
T S Ary, Director 






C\ 



V 



> 



<b 



^ 



Q' 




Library of Congress Cataloging in Publication Data: 



Hamak, John E. 














Analyses of natural gases, 


1988 / by J. 


E. Ilamak and Stella Siglcr. 






p. cm. (Information 


circular) 












Bibliography: p. 66 














Supt. of Docs, no.: I 28.27:9225. 












1. Gas, Natural-United Statcs-Analys 


s. I. Siglc 


r, Stella. II. 


Title. 


III. 


Scries: 


Information circular (United States. Bureau of Mines); 9225. 








TN295.U4 [TP350] 


622 s- 


■dc20 


[665.T3] 




89-600145 














CIP 



CONTENTS 

Page 

Abstract 1 

Introduction 2 

Geologic provinces of the United States 2 

Tables 8 

Previous publications in this series 66 

ILLUSTRATION 

1. Geologic provinces of the United States 3 

TABLES 

1. Samples from gas and oil wells in the United States 9 

2. Samples from pipelines in the United States 58 

3. Samples from gas and oil wells in foreign countries 65 



ANALYSES OF NATURAL GASES, 1988 

By J. E. Hamak 1 and Stella Sigler 2 



ABSTRACT 

This publication contains analyses and related source data for 165 natural gas samples from 21 States 
and 1 foreign country. Of the total samples, 155 were collected during calendar year 1988. The 
remainder were collected earlier, but releases granting permission to publish were not received until 
1988. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the 
occurrences of helium in natural gases of countries with free market economies. This survey has been 
conducted since 1917. The analyses published herein were made by mass spectrometer and 
chromatograph. 

Petroleum engineer. 
Helium resources survey clerk. 
Section of Helium Resources Evaluation, Branch of Helium Resources, Helium Field Operations, U.S. Bureau of Mines, Amarillo, TX. 



INTRODUCTION 



This U.S. Bureau of Mines publication contains analyses 
and related source data for 165 natural gas samples from 
21 States and 1 foreign country. Of these samples, 155 
were collected during calendar year 1988; 10 samples were 
collected earlier, but releases granting permission to 
publish were not received until 1988. All samples were 
obtained and analyzed as part of U.S. Bureau of Mines 
investigations of the occurrences of helium in natural gases 
of countries with free market economies. This survey has 
been conducted since 1917. The analyses published herein 
were made by the mass spectrometer and chromatograph. 

The results of these investigations are published annual- 
ly to make the information available to the petroleum 
industry and the general public. Thirty-three publications 
have presented the results of 14,929 gas analyses made 
prior to 1988. The first three bulletins (1-3) 3 contain 
analyses and related source data on 5,218 gas samples 
collected from 1917 through 1960; these bulletins have 
been supplemented annually by information circulars (4- 
17, 19-24, 26-30, 32-33) containing 9,711 analyses of sam- 
ples collected since 1960. 

In 1976, a compilation of the analyses made prior to 
1975 was prepared by the U.S. Bureau of Mines and pub- 
lished by the National Technical Information Service of 
the U.S. Department of Commerce (18). This compilation 



contains 10,562 analyses of gas samples from gas and oil 
wells and natural gas pipelines in 37 States and 23 foreign 
countries. In 1982, a compilation of analyses made prior 
to 1981 was published (25). The 1982 publication contains 
12,554 analyses of gas samples from gas and oil wells and 
natural gas pipelines in 39 States and 24 foreign countries 
and includes the analyses from the 1976 publication. The 
latest of these compilations was published in 1987 and 
contains 14,242 analyses made prior to 1986. The samples 
were taken from wells or pipelines in 40 States and 24 
foreign countries (31). 

In addition to being in the publications, all analyses and 
related information published through 1988 are available 
on a magnetic tape file. The tape is available for $210 
from the National Technical Information Service, 
Springfield, VA 22161, phone (703) 487-4650; orders 
should refer to U.S. Bureau of Mines tape PB 89-158661. 

The helium survey program is conducted by soliciting 
natural gas samples throughout the United States and 
other countries with free market economies. Without the 
assistance of the petroleum industry, State and Federal 
agencies, and many individuals engaged in oil and gas 
exploration and production, the helium survey in its 
present scope would not be possible. 



GEOLOGIC PROVINCES OF THE UNITED STATES 



The tables include geologic province codes so each 
sample source can be located within a specific geologic 
province as defined by the Committee on Statistics of 
Drilling of the American Association of Petroleum 
Geologists. 4 These provinces, which are given in the 



Italic numbers in parentheses refer to items in the list of previous 
publications at the end of this report. 

4 Mcyer, R. F. Geologic Provinces Code Map for Computer Use. 
AAPG Bull., v. 54, No. 7, July 1970, pp. 1301-1305. 



following list and shown in figure 1, are delineated by 
political boundaries for convenience and for accommoda- 
tion of data processing equipment. Not all of the prov- 
inces shown are gas-producing areas, so many of the codes 
are not used in this publication. Since State or Federal 
ownership is not always known in offshore areas, only one 
code is used for each State. Owing to the lack of informa- 
tion on the location of wells in Alaska, only one code, 972, 
is used for all wells. 

The following list and figure 1 are taken from the 
article cited in footnote 4. 




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Code Province 

100 New England Province 

110 Adirondack Uplift 

120 Atlantic Coast Basin 

130 South Georgia-North Florida Sedimentary Province 

140 South Florida Province 

150 Piedmont-Blue Ridge Province 

160 Appalachian Basin 

200 Warrior Basin 

210 Mid-Gulf Coast Basin 

220 Gulf Coast Basin 

230 Arkla Basin 

240 Desha Basin 

250 Upper Mississippi Embayment 

260 East Texas Basin 

300 Cincinnati Arch 

305 Michigan Basin 

310 Wisconsin Arch 

315 Illinois Basin 

320 Sioux Uplift 

325 Iowa Shelf 

330 Lincoln Anticline 

335 Forest City Basin 

340 Ozark Uplift 

345 Arkoma Basin 

350 South Oklahoma Folded Belt Province 

355 Chautauqua Platform 

360 Anadarko Basin 

365 Cherokee Basin 

370 Nemaha Anticline 

375 Sedgwick Basin 

380 Salina Basin 

385 Central Kansas Uplift 

390 Chadron Arch 

395 Williston Basin 

400 Ouachita Tectonic Belt Province 

405 ■ Kerr Basin 

410 Llano Uplift 

415 Strawn Basin 

420 Fort Worth Syncline 

425 Bend Arch 

430 Permian Basin 

435 Palo Duro Basin 

440 Amarillo Arch 

445 Sierra Grande Uplift 

450 Las Animas Arch 

455 Las Vegas-Raton Basin 

460 Estancia Basin 

465 Orogrande Basin 

470 Pedregosa Basin 

475 Basin-and-Range Province 



Code Province 

500 Sweetgrass Arch 

505 Montana Folded Belt Province 

510 Central Montana Uplift 

515 Powder River Basin 

520 Big Horn Basin 

525 Yellowstone Frovince 

530 Wind River Basin 

535 Green River Basin 

540 Denver Basin 

545 North Park Basin 

550 South Park Basin 

555 Eagle Basin 

560 San Luis Basin 

565 San Juan Mountain Province 

570 Uinta Uplift 

575 Uinta Basin 

580 San Juan Basin 

585 Paradox Basin 

590 Black Mesa Basin 

595 Piceance Basin 

600 Northern Cascade Range-Okanagan Province 

605 Eastern Columbia Basin 

610 Idaho Mountains Province 

615 Snake River Basin 

620 Southern Oregon Basin 

625 Great Basin Province 

630 Wasatch Uplift 

635 Plateau Sedimentary Province 

640 Mojave Basin 

645 Salton Basin 

650 Sierra Nevada Province 

700 Bellingham Basin 

705 Puget Sound Province 

710 Western Columbia Basin 

715 Klamath Mountains Province 

720 Eel River Basin 

725 Northern Coast Range Province 

730 Sacramento Basin 

735 Santa Cruz Basin 

740 Coastal Basins 

745 San Joaquin Basin 

750 Santa Maria Basin 

755 Ventura Basin 

760 Los Angeles Basin 

765 Capistrano Basin 

800 Heceta Island Area 

805 Keku Islands Area 

810 Gulf of Alaska Basin 

815 Copper River Basin 

820 Cook Inlet Basin 



Code Province 

830 Kandik Province 

835 Kobuk Province 

840 Koyukuk Province 

845 Bristol Bay Basin 

850 Bethel Basin 

855 Norton Basin 

860 Selawik Basin 

863 Yukon Flats Basin 

865 Lower Tanana Basin 

867 Middle Tanana Basin 

870 Upper Tanana Basin 

873 Galena Basin 

875 Innoko Basin 

877 Minchumina Basin 

880 Holitna Basin 

885 Arctic Foothills Province 

890 Arctic Slope Basin 

900 Maine Atlantic offshore-general 

901 Maine Atlantic offshore-State 

902 Maine Atlantic offshore-Federal 

903 New Hampshire Atlantic offshore-general 

904 New Hampshire Atlantic offshore-State 

905 New Hampshire Atlantic offshore-Federal 

906 Massachusetts Atlantic offshore-general 

907 Massachusetts Atlantic offshore— State 

908 Massachusetts Atlantic offshore-Federal 

909 Rhode Island Atlantic offshore-general 

910 Rhode Island Atlantic offshore-State 

911 Rhode Island Atlantic offshore-Federal 

912 Connecticut Atlantic offshore-general 

913 Connecticut Atlantic offshore-State 

914 Connecticut Atlantic offshore-Federal 

915 - New York Atlantic offshore-general 

916 New York Atlantic offshore-State 

917 New York Atlantic offshore-Federal 

918 New Jersey Atlantic offshore-general 

919 New Jersey Atlantic offshore— State 

920 New Jersey Atlantic offshore-Federal 

921 Delaware Atlantic offshore-general 

922 Delaware Atlantic offshore-State 

923 Delaware Atlantic offshore-Federal 

924 Maryland Atlantic offshore-general 

925 Maryland Atlantic offshore-State 

926 Maryland Atlantic offshore-Federal 

927 Virginia Atlantic offshore-general 

928 Virginia Atlantic offshore-State 

929 Virginia Atlantic offshore-Federal 

930 North Carolina Atlantic offshore-general 

931 North Carolina Atlantic offshore-State 

932 North Carolina Atlantic offshore-Federal 

933 South Carolina Atlantic offshore-general 

934 South Carolina Atlantic offshore-State 



Code Province 

935 South Carolina Atlantic offshore-Federal 

936 Georgia Atlantic offshore-general 

937 Georgia Atlantic offshore-State 

938 Georgia Atlantic offshore-Federal 

939 Florida Atlantic offshore-general 

940 Florida Atlantic offshore-State 

941 Florida Atlantic offshore-Federal 

942 Florida Gulf of Mexico offshore-general 

943 Florida Gulf of Mexico offshore-State 

944 Florida Gulf of Mexico offshore-Federal 

945 Alabama Gulf of Mexico offshore-general 

946 Alabama Gulf of Mexico offshore-State 

947 Alabama Gulf of Mexico offshore-Federal 

948 Mississippi Gulf of Mexico offshore-general 

949 Mississippi Gulf of Mexico offshore-State 

950 Mississippi Gulf of Mexico offshore-Federal 

951 Louisiana Gulf of Mexico offshore-general 

952 Louisiana Gulf of Mexico offshore-State 

953 Louisiana Gulf of Mexico offshore— Federal 

954 Texas Gulf of Mexico offshore-general 

955 Texas Gulf of Mexico offshore-State 

956 Texas Gulf of Mexico offshore-Federal 

957 California Pacific offshore-general 

958 California Pacific offshore-State 

959 California Pacific offshore-Federal 

960 Oregon Pacific offshore-general 

961 Oregon Pacific offshore-State 

962 Oregon Pacific offshore-Federal 

963 Washington Pacific offshore-general 

964 Washington Pacific offshore-State 

965 Washington Pacific offshore-Federal 

972 Alaska Arctic offshore-general 

973 Alaska Arctic offshore-State 

974 Alaska Arctic offshore-Federal 

975 Alaska Bering Sea offshore-general 

976 Alaska Bering Sea offshore-State 

977 Alaska Bering Sea offshore-Federal 

978 Alaska Pacific offshore-general 

979 Alaska Pacific offshore-State 

980 Alaska Pacific offshore-Federal 

987 Minnesota Lake Superior offshore 

988 Wisconsin Lake Superior offshore 

989 Michigan Lake Superior offshore 

990 Indiana Lake Michigan offshore 

991 Illinois Lake Michigan offshore 

992 Wisconsin Lake Michigan offshore 

993 Michigan Lake Michigan offshore 

994 Michigan Lake Huron offshore 

995 Michigan Lake Erie offshore 

996 Ohio Lake Erie offshore 

997 Pennsylvania Lake Erie offshore 

998 New York Lake Erie offshore 

999 New York Lake Ontario offshore 



TABLES 

The following tables include the results of analyses and related source data from the gas samples, which are divided 
into three groups as follows: 

Table l.-Samples from gas and oil wells in the United States. 

Table 2.-Samples from pipelines in the United States. 

Table 3.-Samples from gas and oil wells in foreign countries. 

The following list indicates the sources of the samples listed in the tables: 





Number 






Number 




Source 


of 
samples 


Tables 


Source 


of 
samples 


Tables 


Alabama 


1 




New York 


1 


1 


Arkansas 


15 




North Dakota . . . 


1 


1 


California 


1 




Oklahoma 


35 


1 


Colorado 


7 


1,2 


Pennsylvania .... 


1 


1 


Indiana 


1 




Texas 


39 


1 




6 




Utah 


1 


2 


Kentucky 


3 




Virginia 


2 


1 




17 


1,2 


West Virginia . . . 


7 


1 




3 




Wyoming 


8 


1 


Mississippi 


4 










Montana 


1 




Spain 


1 


3 


New Mexico .... 


10 


1,2 









All components of the analyses in the tables are reported to the nearest 0.1 percent, except helium, which is reported 
to the nearest 0.01 percent. The word "trace" is used to denote quantities of helium of less than 0.005 percent and 
quantities of other components of less than 0.05 percent. 



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66 



PREVIOUS PUBLICATIONS IN THIS SERIES 



1. Anderson, C. C, and H. H. Hinson. Helium-Bearing Natural 
Gases of the United States. Analyses and Analytical Methods. 
BuMines B 486, 1951, 141 pp. 

2. Boone, W. J., Jr. Helium-Bearing Natural Gases of the United 
States. Analyses and Analytical Methods. Supplement to Bull. 486. 
BuMines B 576, 1958, 117 pp. 

3. Munnerlyn, R D., and R D. Miller. Helium-Bearing Natural 
Gases of the United States. Analyses. Second Supplement to Bull. 486. 
BuMines B 617, 1963, 93 pp. 

4. Miller, R D., and G. P. Norrell. Analyses of Natural Gases of 
the United States, 1961. BuMines IC 8221, 1964, 148 pp. 

5. . Analyses of Natural Gases of the United States, 1962. 

BuMines IC 8239, 1964, 120 pp. 

6. . Analyses of Natural Gases of the United States, 1963. 

BuMines IC 8241, 1965, 102 pp. 

7. Moore, B. J., R D. Miller, and R D. Shrewsbury. Analyses of 
Natural Gases of the United States, 1964. BuMines IC 8302, 1966, 
144 pp. 

8. Moore, B. J., and R D. Shrewsbury. Analyses of Natural Gases 
of the United States, 1965. BuMines IC 8316, 1966, 181 pp. 

9. . Analyses of Natural Gases, 1966. BuMines IC 8356, 1967, 

130 pp. 

10. . Analyses of Natural Gases, 1967. BuMines IC 8395, 1968, 

187 pp. 

11. Cardwell, L. E., and L. F. Benton. 



17. 



_. Analyses of Natural Gases, 1974. BuMines IC 8684, 1975, 



Analyses of Natural Gases, 

Analyses of Natural Gases, 1969. BuMines IC 8475, 1970, 

Analyses of Natural Gases, 1970. BuMines IC 8518, 1971, 

Analyses of Natural Gases, 1971. BuMines IC 8554, 1972, 

Analyses of Natural Gases, 1972. BuMines IC 8607, 1973, 
104 pp. 

16. Moore, B. J. Analyses of Natural Gases, 1973. BuMines IC 8658, 
1974, 96 pp. 



1968. BuMines IC 8443, 1970, 169 pp. 

12. _ 
134 pp. 

13. _ 
130 pp. 

14. _ 
163 pp. 

15. 



122 pp. 

18. . Analyses of Natural Gases, 1917-74. BuMines CP 1-76, 

1976, 889 pp.; NTIS PB 251-202. 

19. . Analyses of Natural Gases, 1975. BuMines IC 8717, 1976, 

82 pp. 

20. . Analyses of Natural Gases, 1976. BuMines IC 8749, 1977, 

94 pp. 

21. . Analyses of Natural Gases, 1977. BuMines IC 8780, 1978, 

95 pp. 

22. . Analyses of Natural Gases, 1978. BuMines IC 8810, 1979, 

113 pp. 

23. . Analyses of Natural Gases, 1979. BuMines IC 8833, 1980, 

100 pp. 

24. . Analyses of Natural Gases, 1980. BuMines IC 8856, 1981, 

236 pp. 

25. . Analyses of Natural Gases, 1917-80. BuMines IC 8870, 

1982, 1055 pp. 

26. Miller, R D., and F. R Hertweck, Jr. Analyses of Natural Gases, 
1981. BuMines IC 8890, 1982, 84 pp. 

27. . Analyses of Natural Gases, 1982. BuMines IC 8942, 1983, 

100 pp. 

28. Hertweck, F. R, Jr., and D. D. Fox. Analyses of Natural Gases, 

1983. BuMines IC 8993, 1984, 127 pp. 

29. Moore, B. J., and J. E. Hamak. Analyses of Natural Gases, 1984. 
BuMines IC 9046, 1985, 102 pp. 

30. Moore, B. J., and S. Sigler. Analyses of Natural Gases, 1985. 
BuMines IC 9096, 1986, 182 pp. 

31. . Analyses of Natural Gases, 1917-85. BuMines IC 9129, 

1987, 1197 pp. 

32. . Analyses of Natural Gases, 1986. BuMines IC 9167, 1988, 

101 pp. 

33. _ 
74 pp. 



Analyses of Natural Gases, 1987. BuMines IC 9188, 1988, 



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